FWIW, I've been cellaring for 13 years now, and I don't worry about all of this. If a tin has some microscopic seal issue, then so what. I've never had an issue, nor do I intend to live more than 20 more years. As a smoker, I will be happy to just live ten more years. I've not yet had any issues, nor will I be devastated if I lose a few tins. That's the risk I take.
I just periodically go through and try to open the tins with bare hands. A sealed tin will not open this way. And, I have yet to find one that has failed. If I do find one, I'll just smoke it.
I'm more suspicious on the seals of the jars, than the tins. If you go check out forums and websites devoted to jarring and canning foods, you'll know what I mean. They are not designed to create a seal by just cranking down the ring on the lid. Use a feeler gauge. Check it out.
And, I am not sold on this mylar crap. Ever open a package with an old harddrive in it? The mylar can just break up by touching it.
If the tins are not 100% assurity, then nothing is, and that's the risk we all take. I'm good with that.